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Pyrite en.wikipedia.org The mineral pyrite, or iron pyrite, is iron disulfide, FeS2. It has isometric crystals that usually appear as cubes. The cube faces may be striated (parallel lines on crystal surface or cleavage face) as a result of alternation of the cube and pyritohedron faces. Pyrite also frequently occurs as octahedral crystals and as pyritohedra (a dodecahedron with pentagonal faces). It has a slightly uneven and conchoidal fracture, a hardness of 6–6.5, and a specific gravity of 4.95– 5.10. It is brittle, meaning it breaks or powders easily. Its metallic luster and pale-to-normal brass-yellow hue have earned it the nickname fool's gold, but ironically, small quantities of actual gold are sometimes found in pyrite. In fact, such auriferous pyrite is a valuable ore of gold. Pyrite is the most common of the sulfide minerals. It is usually found associated with other sulfides or oxides in quartz veins, sedimentary rock and metamorphic rock, as well as in coal beds, and as the replacement mineral in fossils. Pyrite exposed to the environment during mining and excavation reacts with oxygen and water to form sulfuric acid, resulting in acid mine drainage. This results from the action of Thiobacillus bacteria, which generate their energy by using oxygen to oxidize ferrous iron (Fe2+) to ferric iron (Fe3+). The ferric iron in turn reacts with pyrite to produce ferrous iron and sulfuric acid. The ferrous iron is then available for oxidation by the bacteria; this cycle can continue until the pyrite is exhausted.... www.galleries.com Pyrite is a polymorph of marcasite, which means that it has the same chemistry, FeS2, as marcasite; but a different structure and therefore different symmetry and crystal shapes. Pyrite is difficult to distinguish from marcasite when a lack of clear indicators exists. Pyrite's structure is analogous to galena's structure with a formula of PbS. Galena though has a higher symmetry. The difference between the two structures is that the single sulfur of galena is replaced by a pair of sulfurs in pyrite. The sulfur pair are covalently bonded together in essentially an elemental bond. This pair disrupts the four fold symmetry that a single atom of sulfur would have preserved and thus gives pyrite a lower symmetry than galena. Although pyrite is common and contains a high percentage of iron, it has never been used as a significant source of iron. Iron oxides such as hematite and magnetite, are the primary iron ores. Pyrite is not as ecomonical as these ores possibly due to their tendency to form larger concentrations of more easily mined material. Pyrite would be a potential source of iron if these ores should become scarce. |
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